Well, an important question is whether the child has a parent or parents in the church or if he is a bus route student or someone with unsaved parents.
If he has at least one parent who is well settled in the church, you can always tell him that if he doesn't like Sunday School so bad that he has to throw fits, it's okay, you'll let him sit with his parent.
Otherwise, it can be a little harder. I have a student who used to be really strong willed but is really getting it under control now. Some things I've done in the past include:
Making a chart on the wall with every kid's name and giving them three cards; red, yellow and green. Each class every student begins with greeen. If they act up (beyond normal childish things, obviously) they pull a card, so the next is yellow. So forth until they are on red, and if they have to pull the red card, I will either send them into the sanctuary to sit with their parents or I will take them out into the hall and have a talk with them, usually making them tell me why we had to leave class, make them tell you what they can do to behave better, and then pray with them. Sometimes you have to do this several times, but eventually they do start acting better. This is usually the case with kids who just need attention, who are testing boundaries, or who want to see if you'll just get rid of them or actually care enough to keep them around.
My next theme that I'm starting next week is Monopoly, and so each kid is going to get $300. Each time they act up I'm going to have them pay me $100, and if they go "bankrupt", then I proceed with the disciplinary action.
You could try distracting them as much as possible too. It's okay to single him out to "be responsible for the coloring pages" by making him hold them. Sometimes this helps them be so focused on a task that they don't even think about acting up. With my stong willed student this works wonders. He feels needed and valued and loves helping out. You could talk to them privately before that and tell him that you need him to help with the song actions or that you know God really values his prayers so ask him if he'll pray for the class with you. Anything along these lines helps!
One thing I do for kids who outrightly rebel and disrespect me (or any asst teacher I have in there), is I make them apologize in front of the class. Make sure you tell the class this is what will happen when you go over the rules (good idea to do a quick run through before each class). Don't make it a surprise on them. If they know they're going to have to do it, usually that's a good preventive measure. I always tell them when we discuss rules "if you're able to be mean in front of the class, you're able to apologize in front of the class." I've had two students test this one. Needless to say, they've each only ever done it once.
I keep the class rules so simple even the youngest child can recite it "Respect God, Respect People, Respect Things." I have this posted on the wall at all times. Reinforce that respect means "be nice to" several times b/c little kids usually have no clue what that means, but once they do, the kids will call out each other and say, "You're not respecting God by talking while we pray!" or something like that. Now they remind each other

YAY!
All this said, sometimes it just takes a lot of prayer and patience on the teacher's part. I've been working with my one strong willed child for about three years now and he's really gotten better. Last week at snack he actually called out loudly, and the first one to do so, "Thank you for our snack!" When he's good in class, too, I make sure to shake his hand and tell him thank you (and point out good things he's done) afterwards. His mom is down on hm a lot, so I usually do it where she can overhear us. Sometimes I go and brag about him to her about how great he was.
Oh, I should add that my church does "Children's Church" as opposed to the tradition Sunday School class structure, so I have children from pre-k up! (about 4-12), and these tactics seem to work for every age level. It's definitely been a trial and error process over time but once you find what works stick with it! Keep going on with what you're doing God will bless you greatly!