No. The council APPROVED the books that were already in use.
So again, Biblical evidence requires you to refer to Bible passages which you did not do here.
.
What was in use?
If you study the Fathers and Divided into time periods, here is what the Fathers thought:
30 a.d. - 160 a.d.
Summary - The New Testament is not clearly distinguished from other Christian writings.
Gospels - Generally accepted by 130
Justin Martyr's "Gospels" contain apocryphal material
Polycarp was the first to use the four Gospels we have today.
Pauline Writings - Generally accepted by 130, though quotations from them are rarely introduced as scriptural.
Acts - Scarcely known or quoted from
Philippians, 1 Timothy - Rejected as scriptural by Justin Martyr
2 Timothy, Titus, Philemon - Rejected as scriptural by Polycarp and Justin Martyr
Hebrews - Not considered canonical by majority, and expressly rejected as scriptural by Polycarp and Justin Martyr
James - Not considered canonical, and never quoted from; expressly rejected as scriptural by Polycarp and Justin Martyr
1 Peter - Not considered canonical
2 Peter - Not considered canonical and never cited
1,2,3 John - Not considered canonical and rejected as scriptural by Justin Martyr, and partially rejected by Polycarp
Jude - Not considered canonical and rejected as scriptural by Polycarp and Justin Martyr
Revelation - not canonical and rejected as scriptural by Polycarp
Ignatius of Antioch was unaware of half the Gospels and the majority of the Pauline writings.
160 a.d.- 250 a.d.
Summary - Awareness of a Canon begins toward the end of the 2nd century. Tertullian and Clement of Alexandria were the first to use the phrase "New Testament" in the 2nd and 3rd century.
Gospels - Accepted
Acts - Gradually accepted
Pauline Writings - Accepted with certain exceptions
2 Timothy - Rejected by Clement
Philemon - Rejected by Irenaeus, Origen, Tertullian, and Clement
Hebrews - Not considered canonical until the 4th century in the West. Disputed by Origen. First accepted by Clement.
James - Not canonical. First mentioned and disputed by Origen. Rejected by Irenaeus, Tertullian, and Clement
1 Peter - Gradual acceptance. First accepted by Irenaeus and Clement
2 Peter - Not canonical. First mentioned and disputed by Origen. Rejected by Irenaeus, Tertullian, and Clement
1 John - Gradual acceptance. First accepted by Irenaeus, and rejected by Origen.
2 John - Not canonical. Disputed by Origen and rejected by Tertullian and Clement
3 John - Not canonical. Disputed by Origen and rejected by Tertullian and Clement
Jude - Gradual acceptance. Accepted by Clement and rejected by Origen.
Revelation - Gradual acceptance. First accepted by Clement and rejected by the Barococcio Canon of 206
Epistle of Barnabas - Accepted by Clement
Shepherd of Hermas - Accepted by Irenaeus, Tertullian, Origen, and Clement
The Didache - Accepted by Clement
The Apocalypse of Peter - accepted by Clement
The Acts of Paul - Accepted by Clement, and appears in Greek, Latin, Syriac, Armenian, and Arabic translations
Gospel of Hebrews - Accepted by Clement. Accepted by Muratorian Canon of 190 which excluded Hebrews, James, 1 Peter, 2 Peter, and included The Apocaplypse of Peter and Wisdom of Solomon.
250 a.d. 325 a.d.Summary - The Catholic epistles and Revelation are still being disputed
The Catholic, or general, epistles are the terms sometimes used for the letters written by James, Peter, John, and Jude. They are so called because they are addressed to Christians in general, not to any church or person in particular such as the epistles to the Corinthians, Thessalonians etc. The word "catholic" originated from Greek and then Latin words which simply meant throughout the whole.
Gospels, Acts, Pauline Writings - Accepted
Hebrews - Accepted in the East. Disputed and rejected in the West.
James - Disputed and rejected in the East, and rejected in the West.
1 Peter - Fairly well accepted
2 Peter - Still disputed
1 John - Fairly well accepted
2, 3 John, Jude - Still disputed
Revelation - Disputed, especially in the East. Rejected by Dionysius
Council of Nicaea (325 a.d.)
Questions canonicity of James, 2 Peter, 2 John, 3 John, and Jude
From 325 a.d. to Council of Carthage (397 a.d.)
Summary - St. Athanasius first lists our present 27 New Testament books as such in 367 a.d. Disputes still persist concerning several books, almost right up until 397, when Canon is authoritatively closed.
Gospels, Acts, Pauline Writings, 1 Peter, 1 John - Accepted
Hebrews - Eventually accepted in West
James - Slow acceptance. Not even quoted in the West until around 350 a.d.!
2 Peter - Eventually accepted
2, 3 John, Jude - Eventually accepted
Revelation - Eventually accepted. Rejected by Cyril, John Chrysostom, Gregory Nazianzen
Epistle of Barnabas - Accepted by Codex Sinaiticus in late 4th century
Shepherd of Hermas - Accepted by Codex Sinaiticus in late 4th century. Used as a textbook for catechumens (those studying to become Christian).
1 Clement, 2 Clement - Accepted by Codex Alexandrinus in late 5th century!