Before.After.
As I understand it, heat is the total amount of kinetic and potential energy in an object, whereas temperature is the average amount of heat.
So pouring room-temperature cream into a cup of hot coffee, then leaving to answer the phone, will give the coffee time to reach thermal equilibrium between the coffee and the cream.
Unless, of course, I'm wrong.
The basic physics of heat provides the answer: you should add the cream to your coffee before answering the phone. Coffee with cream cools about 20% slower than black coffee, for three reasons:
- Black coffee is darker. Dark colors absorb heat faster than light colors (just think about wearing a black T-shirt versus a white T-shirt on a hot, sunny day). But dark colors also emit heat faster than light colors. Absorption and emission are essentially two sides of the same coin. So by lightening the color of your coffee, you slow its rate of heat loss slightly.
- Stefan-Boltzmann says so. The Stefan-Boltzmann law says that hotter surfaces radiate heat faster specifically, the power of emission is proportional to the temperature (in kelvin) raised to the fourth power. So let's say you have two cups of coffee that start at the same temperature. You pour cream in cup #1 and the coffee drops in temperature immediately. But the rate at which it loses heat also drops. Meanwhile, the hotter black coffee in cup #2 cools so rapidly that within five minutes the two coffees are at about the same temperature. But you still haven't added the cream to coffee #2! When you do, it cools even more; cup #1 is now the hotter of the two.
- Viscosity versus evaporation. This is the clincher. Adding cream thickens the coffee (adds viscosity), so it evaporates slower. You'd be surprised just how much heat evaporation carries away. Slow the rate of evaporation and you avoid a lot of that heat loss. (This is also one big reason that coffee stays warm longer with a lid on the cup.)
The point is the answer requires a knowledge of science, not a personal opinion and certainly not living in a make believe world where anything is possible but in reality science limits the options.
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