I'm going to repeat myself because I have more time to be more specific here. After reading this passage about a dozen times, I'm still at a total loss as to how they conclude that C14/C12 ratio changed with the removal of 99% of the biomass.
ICR said:
A conservative estimate for the pre-Flood biomass is 100 times that of today. If one takes as a rough estimate for the total 14C in the biosphere before the cataclysm as 40% of what exists today and assumes a relatively uniform 14C level throughout the pre-Flood atmosphere and biomass, then we might expect a 14C/12C ratio of about 0.4% of today's value in the plants and animals at the onset of the Flood. With this more realistic pre-Flood 14C/12C ratio, we find that a value of 0.24 pmc corresponds to an age of only 4200 years (0.004 x 2-4200/5730 = 0.0024 = 0.24 pmc). Even though these estimates are rough, they illustrate the crucial importance of accounting for effects of the Flood cataclysm when translating a 14C/12C ratio into an actual age.
What Dr. Baumgardner has done is claim that the earth had at least 100 times more biomass before the flood. I'd still like a reference or some kind of support for that, but that's not the problem here so I'll assume it for the moment.
He then claims that there was about 40% as much C14 in the atmosphere as today (apparently another unsupported assumption, but I'll play along here too -- though it should be noted that tree rings and ice cores have been calibrated back over 10,000 years without any such findings).
Then he does something really weird. He says that we might expect a C14/C12 ratio of about 0.4% of today's value based on these numbers.
Apparently he is guessing at the 40% TOTAL C14, and then saying that the total C12 was the same. But here's a huge mistake -- he apparently claims that this 0.4/1 (the C14/C12 ratio relative to modern values) should be divided by the difference in the amount of biomass to get 0.004 times the C14/C12 ratio.
Unless I'm missing something huge, this is an extreme mathematical error -- something that should CERTAINLY call into question the value of any ICR "peer review" process!
Since plants absorb C14 and C12 equally, a ratio that is lower at 40% of modern values would leave a C14/C12 ratio on plants
totally independent of the amount of biomass on the planet. He's apparently decided to multiply the (entirely arbitrary) lower ratio by the ratio of plant life today to (entirely arbitrary) estimates of plant life then to get 0.4%.
This would only be valid if plants absorb ONLY C14 and not C12 -- in that case the C14 levels would drop by the amount of biomass taken out of the system (claiming 99%) while the C12 levels would remain constant. What actually happens in nature is that plants do not distinguish between C14 and C12 and absorb them equally.
I'm totally at a loss as to how a Ph.D. could make such bogus claims, and to how the editorial staff that claims to review the scientific content of the work would allow such a thing to be published...
[EDIT]I took a look at his credentials, and apparently he got a Ph.D. in electrical engineering and then went back for a Ph.D. in geophysics for the sole purpose of looking qualified to talk on creationist matters. While I don't doubt the quality of his education in either of his degrees, when he makes such huge mistakes by assuming that plants absorb C14 and not C12 I question his commitment to accuracy given that his stated purpose for getting the second Ph.D. was not to advance our knowledge but to look credible to creationists and non-creationists on these topics.[/EDIT]