How often do you see radical formation in ESI fragmentation?

[james bowers]

I've found a few unknown identification papers and the occasional mechanism contains a radical. Some people I've discussed fragmentation with say you shouldn't see radical formation at all in ESI MS/MS. Trying to form my own opinion but could use more information.

Links to articles or advice from personal experience appreciated.

 

[Danielwright2311]

Are we talking about molecules here?

 

[section9+1]

Personal experience??

 

[Sound Doctrine]

Please identify the acronyms. I am not familiar with them.

 

[Danielwright2311]

I found this article

I hope it helps you

Principles and Applications of Liquid Chromatography-Mass Spectrometry in Clinical Biochemistry

 

[tampasteve]

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