I am not a biochemist, however I believe the biochemistry literature is replete with such estimations, but with a twist as I will discuss further on down. Just a brief flip through the 20 year old biochem textbook that I have at home establishes quite a few potential reactions.
I honestly don't know what it is you
want here. I guess what you want is someone to produce a
statistical probability for life to have occurred. I can tell you precisely what that statistical probability would
NOT look like. You can see it
here.
What you seem
intent on doing in this thread is
demanding that the chemistry be ignored. So far you've run up against a geochemist (me), a polymer/organic chemist (Maneki) and a couple of biochem students on this board who tell you your
simplifications are so oversimplified that your model fails at the start.
That's what we've been trying to tell you all along. We are looking at a system that is complex but whose individual parts are not
statistically impossible. The reactions described have been done. The Miller Urey experiment
actually produced important organic precursors to life and the Oro experiment produced an
actual biologically important nitrogenous base. One that we find in DNA and RNA.
Let me outline for you the
real favorable assumptions you left out of your model:
1. Early earth with a reducing atmosphere. You have so far only found some discussion of a later atmosphere that was, at worst, possibly "neutral" but still capable of sustaining some of these reactions. But life, as has been pointed out, left evidence it was around before this "neutral atmosphere" was in play.
2. Available energy sources (lightning, possibly UV, geothermal heat)
3. Available water
4. Potential catalytic surfaces (silicates, sulfides, etc.)
NOW, when you run the "statistics" you need to:
A. Actually model the reactions necessary. That means establish the
reaction kinetics, and then the
thermodynamics to determine what reactions are more likely and what reactions are limited by speed.
B. Factor in the catalytic mineral surfaces' role in removing some kinetic barriers to some of these reactions.
C. Assess the
YIELDS of these reactions.
THEN run your statistical model.
I am not even going to
begin to place numbers on these factors, but I am sure the biochemical literature is quite full of them.
To your knowledge. Which I think we've established as extremely limited in terms of chemistry and biochemistry.
Well, to be fair, the fact that we are all here means life had a 100% chance of occuring in the past. Our differences seem to lie in
exactly how that happened.
You seem to be of the impression that the reactions could not have occurred without God's direct intervention, correct? While science assumes that if all the pieces of the reaction are possible then the overall reaction is far more likely to be possible.
Right now we have all the pieces coming together, but it's a young science.
Think of it this way: You guys have had about 1 million years to "prove" one particular God exists. You in the Judeo-Christian Community have had approximately 5000 years to do your work. So far you are not successful in convincing everyone everywhere that Yahweh is THE God.
Science has had only about 50 years since Miller-Urey to put the system together. Cut us some slack.
No, but you most assuredly need to
understand the system you are working with. Your simplification is so oversimplified it ignores the actual system.
Imagine if you will that I wish to estimate the cost of Air Force Aircraft by the following assumptions:
1. Airplanes cost a lot.
2. 1 trillion is a lot.
3. The Air force has a lot of airplanes
Result: The Airforce has 1 trillion airplanes at 1 trillion dollars a piece which means the total cost of the U.S. airforce airplanes is $1X10[sup]24[/sup].
Do you see the error here? I have failed to constrain one of the important variables.
I have oversimplified the assumptions and made a fatal flaw. In the case of your assumptions you made a gross oversimplification that ignores all the details:
In reaction rate kinetics there's an expression called the Arrhenius equation that describes the very thing you have oversimplified here.
The A in the equation, the "pre-exponential" factor is often called the "Frequency Factor" and tell us something about the frequency of collisions
and their orientation, because sometimes orientation (how the molecules are arranged and facing each other) factors into the "success" of a reaction.
In addition the little E[sub]a[/sub] term tells us how energetically the collision must be to be successful.
A and Ea are set by the reaction which means that in order to
actually model the countless reactions involved would mean that you have to know which reactions you are talking about. Not just randomly
decree that you give it all a 50% chance of occuring.
This is also where
catalytic surfaces like mineral surfaces come into play. A catalyst won't make a thermodynamically disfavorable reaction occur, but what it will do is LOWER the E[sub]a[/sub] of the reaction rate and make it more kinetically favorable to occur.
This is why it is important to not take your oversimplified systems too far. You cannot assess a random "chance" factor like a coinflip to these analyses.
"Estimates" of the kind you seem to want are probably available assuming certain reaction pathways. I think the actual facts on the ground are that we are still gathering the reaction pathways.